In this strudy, the traceability of Rivaroxaban-related impurities was investigated based on the synthesis route of Rivaroxaban as well as the quality standard of imported Rivaroxaban. The synthesis and 1 H NMR characterization of the corresponding Rivaroxaban impurities A, B and E-G were also carried out, which will be helpful to the studies of quality control of Rivaroxaban raw material.